The anime is set immediately after the main storyline's Sanctuary arc after the defeat of Gemini Saga from Masami Kurumada's original Saint Seiya manga, but before the Posieidon arc. However, whereas the original manga followed a boy named Seiya and other Saints who fight to protect the goddess Athena, the new series follows a female "Saintia" named Shō who fights evil deities to protect Athena.
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(Source: Anime News Network)

Episode 1 - The Fated Sisters! Shoko and Kyoko

Episode 2 - Individual Decisions! The Goddess and Saintias

Episode 3 - Blooming in Darkness! The Dryads of Eris

Episode 4 - The Reunion of Sorrow! The Bond of the Separated Sisters

Episode 5 - Fly! Like Pegasus

Episode 6 - Colliding Souls! Saori vs. Grand Master

Episode 7 - The Battle of the Twelve Temples! The Allurement of the Terrifying Ghosts

Episode 8 - A Clash of Nightmare! The Fists of Leo Flare Up

Episode 9 - A Spiral of Conflict! The Golden Apple and Orion's Devotion

Episode 10 - Shine Saintias! At the End of a Noble Prayer

GONZO

Toei Animation

Saint Seiya Saintia Sho